4.5 Review

The future of isosorbide as a fundamental constituent for polycarbonates and polyurethanes

期刊

GREEN CHEMISTRY LETTERS AND REVIEWS
卷 14, 期 3, 页码 533-543

出版社

TAYLOR & FRANCIS LTD
DOI: 10.1080/17518253.2021.1965223

关键词

Isosorbide; dimethyl carbonate; diphenyl carbonate; bisphenol-A; diisocyanate

资金

  1. Bio-Based Industries Joint Undertaking (JU) under the European Union's Horizon 2020 research and innovation programme [790440]
  2. European Union's Horizon 2020 research and innovation programme
  3. Bio-Based Industries Consortium
  4. H2020 Societal Challenges Programme [790440] Funding Source: H2020 Societal Challenges Programme

向作者/读者索取更多资源

Isosorbide, as a green raw material, has great potential in the synthesis of polycarbonates and polyurethanes to obtain products with similar or enhanced properties compared to commercial equivalents.
Isosorbide is a biobased compound which could become in the near future an advantageous competitor of petroleum-derived components in the synthesis of polymers of different nature. When the reactivity of isosorbide is not enough, it can be successfully transformed into secondary building blocks, such as isosorbide bis(methyl carbonate), which provides extra functionalities for polymerization reactions with diols or diamines. The present review summarizes the possibilities for isosorbide as a green raw material to be used in the synthesis of polycarbonates and polyurethanes to obtain products of similar or enhanced properties to the commercial equivalents.

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