期刊
ADVANCED ENERGY MATERIALS
卷 11, 期 36, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202101976
关键词
3D skeletons; anode protection; Na-O; (2) batteries; sodiophilicity; sodium-metal batteries
类别
资金
- National Natural Science Foundation of China [52025013, 52071184, 21835004]
- Ministry of Science and Technology of China [2017YFA0206702, 2016YFB0901502]
- 111 Project [B12015]
- Natural Science Foundation of Tianjin [18ZXJMTG00040, 19JCZDJC31800]
- Fundamental Research Funds for the Central Universities
Constructing dendrite-free sodium metal anodes with strong sodiophilicity in 3D carbon skeletons can lead to long cycle life and excellent electrochemical performance in sodium-metal batteries. The co-existence of O and N functional groups on a carbon matrix can regulate Na deposition behavior and facilitate homogeneous Na+ distribution, laying the foundation for high-performance sodium-metal batteries.
Constructing dendrite-free sodium metal anodes with admirable electrochemical performance and long cycle-life is crucial for the practical application of sodium-metal batteries (SMBs). One of the feasible methods is to design 3D skeletons with sodiophilicity. Herein, the density functional theory (DFT) calculations indicate that the co-existence of O and N functional groups on a carbon matrix can imbue strong sodiophilicity, and can regulate the Na deposition behavior to planar extension. Under the guidance of DFT calculation results, robust 3D carbon nanofibers are fabricated with sodiophilic O and N functional groups, which simultaneously facilitates homogeneous Na+ distribution and a dendrite-free construction. The stabilized sodium metal anode achieves an ultra-long cycle life of 1600 h at 1 mA cm(-2) and an overpotential of merely approximate to 22 mV at 4 mA cm(-2) in Na||Na symmetric batteries. Furthermore, superior electrochemical properties are demonstrated in both Na-O-2 cell and a full sodium ion cell using Na3V2(PO4)(3) as a cathode, laying the foundation for the next generation high-performance SMBs.
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