期刊
ADVANCED ENERGY MATERIALS
卷 11, 期 29, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202100967
关键词
defect passivation; dopant-free HTM; inorganic perovskites; MA-free perovskites; perovskite solar cells
类别
资金
- APRC Grant of the City University of Hong Kong [9610421]
- Innovation and Technology Fund [ITS/497/18FP, ITS/095/20]
- ECS grant from the Research Grants Council of Hong Kong [CityU 21301319]
- Natural Science Foundation of Guangdong Province [2019A1515010761]
- Guangdong Major Project of Basic and Applied Basic Research [2019B030302007]
- Guangdong-Hong Kong-Macao joint laboratory of optoelectronic and magnetic functional materials [2019B121205002]
- National Natural Science Foundation of China [NSFC: 51733010, 21672267, 51973239]
The study introduces a novel small molecular hole-transporting material SFDT-TDM based on spirofluorene-dithiolane, synthesized through easy and cost-effective routes, which shows high efficiency and stability in perovskite solar cells.
Developing low-cost, efficient, and stable dopant-free hole-transporting materials (HTMs) in perovskite solar cells (PVSCs) is essential to their commercial deployment. Herein, the synthesis of a novel spirofluorene-dithiolane based small molecular HTM, SFDT-TDM, through facile and low-cost synthetic routes is reported. The C-H (horizontal ellipsis) pi interactions in adjacent SFDT-TDM are beneficial for high hole mobility and the methylthio groups in SFDT-TDM can serve as Lewis bases to passivate the defects on the surface of perovskite films, leading to suppressed non-radiative recombination and enhanced charge extraction at the perovskite/HTM interface. As a result, Cs(x)FA(1-x)PbI(3) based PVSCs with SFDT-TDM as the HTM realize champion power conversion efficiencies (PCEs) of 21.7% and 20.3% for small-area (0.04 cm(2)) and large-area (1.0 cm(2)) devices with negligible photocurrent hysteresis, respectively. Additionally, all-inorganic CsPbI3-xBrx based PVSCs with SFDT-TDM demonstrate an impressive PCE of 17.1% along with excellent stability. This work highlights the great potential of the spirofluorene core for exploring low-cost and dopant-free HTMs for PVSCs with high efficiency and stability.
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