4.8 Article

Electrokinetic and in situ spectroscopic investigations of CO electrochemical reduction on copper

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Summary: The deployment of gas diffusion electrodes (GDEs) for the electrochemical CO2 reduction reaction (CO2RR) has significantly increased current densities, but stability challenges arise due to rapid flooding of GDEs. Research shows that applied potential plays a central role in causing instabilities in carbon gas diffusion layers (GDLs) during CO2RR, leading to independent flooding issues. The study findings can be applied to electrochemical reduction reactions using carbon-based GDEs with cathodic overpotentials less than -0.65 V versus a reversible hydrogen electrode.

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