期刊
WATER SCIENCE AND TECHNOLOGY
卷 84, 期 6, 页码 1354-1365出版社
IWA PUBLISHING
DOI: 10.2166/wst.2021.313
关键词
defect; degradation; graphitic carbon nitride; photocatalytic activity; porous structure
资金
- Natural Science Foundation of Henan [18B150003]
- Henan Provincial Natural Science Outstanding Youth Fund Project [212300410034]
- National Training Program of Innovation and Entrepreneurship for Undergraduates [202010463022]
- Cultivation Programme for Young Backbone Teachers in Henan University of Technology [21420073, 21420108]
The fabrication of porous graphitic carbon nitride (p-C3N4) through pyrolyzing treatment of graphitic carbon nitride (g-C3N4) introduced defects beneficial for electron-hole pair generation and recombination inhibition, leading to higher degradation efficiency and stability.
Porous graphitic carbon nitride (p-C3N4) was fabricated via simply pyrolyzing treatment of graphitic carbon nitride (g-C3N4). The defects could be introduced into the structure of g-C3N4 by the broken of some bonds, which was beneficial for the generation of electron-hole pairs and restraining their recombination. Compared with g-C3N4, p-C3N4 showed a narrow band gap to promote the utilization of visible light. Furthermore, the porous structure also increased the specific surface area to maximize the exposure of active sites and promote the mass transfer during photodegradation. As a result, the as-reported p-C3N4 exhibited considerably higher degradation efficiency for Rhodamine B (RhB) and Methyl Orange (MO) than that of pristine g-C3N4. Moreover, the photocatalyst showed high durability and stability in recycling experiments.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据