Theoretical model for the high-pressure melting process of MgO with the B1 structure

MgO is an abundant mineral in the rocky mantle of terrestrial planets, but its melting behaviors remain enigmatic. Here we introduce a simple theoretical model to investigate the B1-liquid transition of MgO up to 370 GPa. Vibrational free energies of B1-MgO are fully computed by the moment recurrence technique in quantum statistical physics. On that basis, we associate the melting temperature with the isothermal bulk modulus via the work-heat equivalence principle. This strategy allows us to quantitatively explain recent experimental data. Our numerical analyses would yield insights into planetary dynamics and evolution.

Automated summary

The study introduces a theoretical model to investigate the melting behavior of MgO and successfully explains recent experimental data. The numerical analyses provided insights into planetary dynamics and evolution.