A new reactor for process intensification involving the simultaneous application of adjustable ultrasound and microwave radiation

Ultrasound (US) and Microwaves (MW) are effective methods for processes intensification. Their combined use in the same reactor can lead to remarkable results. Recently there has been a resurgence of interest in this field for new synthetic applications using reactors based upon existing technologies. We describe here a new type of apparatus in which the thermal energy is continuously removed from the system making possible the use of high power and adjustable ultrasonic and microwave densities throughout the process. The installation consists of a glass reactor located in a monomode applicator which is immersed at the same time in an ultrasonic device which can be operated at different frequencies and powers. A liquid, transparent to microwaves, was used to couple ultrasonic energy to the reactor and to remove the heat generated. Comsol software was used to get information about the distribution of ultrasonic and microwave energy between the reactor liquid and the coupling fluid. The performance was assessed using the conversion of p-nitrophenol into 4-nitrocatechol as a chemical dosimeter and a transesterification.

Automated summary

This study introduces a new apparatus that allows the use of high power and adjustable ultrasonic and microwave densities throughout a reaction process. A liquid transparent to microwaves is used to couple ultrasonic energy to the reactor and remove generated heat. Comsol software is utilized to analyze the distribution of ultrasonic and microwave energy in the reactor and coupling fluid. The performance of the apparatus is evaluated through chemical dosimeter tests and transesterification reactions.