期刊
TOPICS IN CATALYSIS
卷 64, 期 7-8, 页码 470-480出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-021-01452-x
关键词
Dehydrogenation; Reaction mechanism; Liquid organic hydrogen carrier; Methylcyclohexane; Stability
The technology for storing and transporting hydrogen will be important for the future expansion of renewable energy. Liquid organic hydrogen carriers (LOHCs) have been proposed as a way to store hydrogen in high density, with recent developments focusing on typical LOHCs and key dehydrogenation catalytic processes.
Considering the expansion of the use of renewable energy in the future, the technology to store and transport hydrogen will be important. Hydrogen is gaseous at an ambient condition, diffuses easily, and its energy density is low. So liquid organic hydrogen carriers (LOHCs) have been proposed as a way to store hydrogen in high density. LOHC can store, transport, and use hydrogen at high density by hydrogenation and dehydrogenation cycles. In this review, we will focus on typical LOHCs, methylcyclohexane (MCH), 18H-dibenzyltoluene (DBT), and 12H-N-ethylcarbazole (NECZ), and summarize recent developments in dehydrogenation catalytic processes, which are key in this cycle.
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