期刊
TETRAHEDRON
卷 92, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2021.132274
关键词
Carbene; C-H insertion; Rhodium-catalyzed; Cross-coupling; Conjugated enynones
资金
- NSFC [21871010]
- Laboratory for Synthetic Chemistry and Chemical Biology of Health@InnoHK of ITC, HKSAR
The rhodium-catalyzed directed acyl C-H bonds carbene insertion reaction of 2-aminobenzaldehydes with conjugated enynones has been achieved, providing a series of α-furyl ketone derivatives with good functional group tolerance in moderate to good yields. Carbene migratory insertion is proposed as the key step in this transformation.
A rhodium-catalyzed directed acyl C-H bonds carbene insertion reaction of 2-aminobenzaldehydes with conjugated enynones has been realized, affording a series of a-furyl ketone derivatives in moderate to good yields with good functional group tolerance. Carbene migratory insertion is proposed as the key step in this transformation. (C) 2021 Elsevier Ltd. All rights reserved.
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