期刊
SURFACE & COATINGS TECHNOLOGY
卷 421, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2021.127468
关键词
High-entropy alloy film; Magnetron sputtering; Tribology performance; Corrosion resistance
资金
- National Natural Science Foundation of China [51805063, 51505050]
- Scientific and Technological Research Program of Chongqing Municipal Education Commission, China [KJQN201801134]
- Chongqing Technology Innovation and Application Development Project [cstc2019jscxfxydX0046]
The possibility of high-entropy alloy (CrNbSiTiZr)C was investigated through thermodynamics analysis and successful deposition of the film. The film showed thermodynamic stability at high temperatures and exhibited high nanohardness and superior corrosion resistance in experiments.
The formation possibility of high-entropy alloy (CrNbSiTiZr)C was first studied by analyzing thermodynamics parameters through first-principles calculation. Then, the (CrNbSiTiZr)C film was successfully deposited by reactive radio frequency magnetron sputtering. Theoretical analysis results show that the mixing enthalpy and entropy values of (CrNbSiTiZr)C were 18.45 kJ/mol and 0.805 R, respectively, indicating that (CrNbSiTiZr)C is thermodynamically stable above the temperature of 2758 K. Experimental results show that the concentration of each metal element in the film is near an equimolar ratio and a mixture of Cr3C2, NbC, SiC, TiC, ZrC, and oxide formed in the (CrNbSiTiZr)C film. Moreover, the as-prepared film possesses a single B1 structure with a (111) preferred orientation and exhibits high nanohardness, elastic modulus, and fracture toughness. The friction coefficients and wear rate of the (CrNbSiTiZr)C film is as low as 0.3 and 4.2 x 10(-6) mm(3)/Nin., respectively. The film also shows a superior corrosion resistance in a 3.5 wt% NaCl solution, a positive E-corr and a low i(corr) value of -189 mV and 0.0026 mu A/cm(2), respectively. The film is proposed for industrial applications given its excellent mechanical, tribology, and corrosion performance and based on the theoretical analysis and experiment results.
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