期刊
SOLAR ENERGY MATERIALS AND SOLAR CELLS
卷 227, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.solmat.2021.111114
关键词
Organic photovoltaics; Transparent photovoltaics; Optical simulations; Transfer-matrix simulations; UV-Absorbing photovoltaics; High-voltage photovoltaics
资金
- Arnold and Mabel Beckman Foundation
- National Science Foundation Division of Materials Research [DMR1420541]
Organic solar cells are suitable for semi-transparent applications, requiring a balance between transparency and power generation. By simulating the design of organic UV absorbers and solar cells, it is found that solar cells using absorbers with a cutoff wavelength of 420 nm produce the most power without compromising transparency or color neutrality.
Organic solar cells are ideal for semi-transparent applications given their peaky absorption, which allows them to selectively absorb photons outside the visible range while transmitting visible light. Such devices embody a fundamental tradeoff between transparency and power generation that must be optimized to fit the requirements of each potential application-for example, powering electrically dimmable smart windows. To inform the design of organic ultraviolet-absorbers and solar cells that target such applications, we computer-generate sets of optical constants with a range of absorption coefficients and absorption cutoff wavelengths that mimic those of real organic semiconductors. We then perform optical transfer-matrix simulations to determine the absorption and transmission spectra of full-stack photovoltaic cells, inserting these computer-generated optical constants to describe the photoactive absorbing layers. We find that solar cells having absorbers with a cutoff wavelength of 420 nm produce the most power without degrading transparency or color neutrality, and that absorption coefficients up to 5 x 105 cm 1 are needed to fully absorb the targeted wavelengths within practical photoactive layer thicknesses <300 nm in the absence of a reflecting electrode.
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