期刊
SOLAR ENERGY
卷 224, 期 -, 页码 218-229出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.solener.2021.05.088
关键词
Spray Pyrolysis; Thin Films; Semiconductor; Chalcogenide
资金
- Research Council of Sharif University of Technology (SUT)
This work focused on spray pyrolysis deposition of Cu2SnS3 (CTS) thin films using a stable basic solution. The study investigated the impact of parameters such as substrate temperature and copper concentration on the structural, optical, and electrical properties of the deposited thin films. XRD and Raman analysis confirmed the formation of pure CTS films, and optical studies indicated a band gap between 1.08 and 1.2 eV for different Cu/Sn ratios.
This work focused on the spray pyrolysis deposition of Cu2SnS3 (CTS) thin films using a stable basic solution. The effect of the most important parameters including the substrate temperature and copper concentration on the structural, optical and electrical properties of as-deposited thin films was investigated. Qualified thin films with suitable microstructure and composition could be deposited at 370celcius. XRD and Raman analysis while confirming the pure CTS film formation, show that as the Cu/Sn decreases, the crystal structure layers are changed from the tetragonal phase to the cubic phase mixed with Sn-rich phases. The optical study shows its band gap between 1.08 and 1.2 eV for different Cu/Sn ratios with the absorption coefficient being more than104 cm 1. The Hall and Mott-Schottky measurements reveal that all samples show a p-type behavior and carrier concentration of the samples rise as the Cu/Sn ratio is enhanced. A full spray superstrate solar cell based on CTS (Cu/Sn = 1 with a semiconductor behavior) resulted in an efficiency of 0.63%.
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