4.8 Article

Single-molecule laser nanospectroscopy with micro-electron volt energy resolution

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Article Multidisciplinary Sciences

Single-molecule laser nanospectroscopy with micro-electron volt energy resolution

Hiroshi Imada et al.

Summary: A single-molecule spectroscopic method with micro-electron volt energy and submolecular-spatial resolution has been developed to induce molecular luminescence in scanning tunneling microscopy. The state-selective characterization of energy levels and linewidths of individual electronic and vibrational quantum states of a single molecule has been demonstrated. Tuning energy levels of molecular systems through the Stark effect and plasmon-exciton coupling in the tunneling junction opens up possibilities for creating designed energy-converting functions.

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