期刊
POWDER TECHNOLOGY
卷 386, 期 -, 页码 382-393出版社
ELSEVIER
DOI: 10.1016/j.powtec.2021.03.055
关键词
Transport properties; Continuum percolation; Average excluded area; Finite difference method; Superoval pores
资金
- National Natural Science Foundation of China [51878152, 51978241]
- Ministry of Science and Technology of China -973 Project [2015CB655102]
This study developed a framework to investigate the impact of pore shape polydispersity on the diffusivity of composite materials. A new algorithm was proposed to detect the excluded area of polydisperse-shaped pores, and numerical calculations were carried out using the finite difference method. The reliability of the theoretical framework was validated by comparing with numerical results.
Understanding the effects of the pore shape polydispersity on the percolation and diffusivity of the porous network has a great impact on the assessment and optimization of the composites' durability. In this work, a comprehensive framework is developed to study the effects of the pores' shape polydispersity on composites' diffusivity. In the present framework, the quantitative relationship between pores' shape polydispersity and percolation threshold of porous networks are established by an average excluded area formula (AEAF). Combining AEAF with the generalized effective medium theory (GEMT), the diffusivity of porous composites comprising polydisperse-shaped pores are predicted. To obtain the excluded area of polydisperse-shaped superoval particles, a new algorithm is proposed to detect whether the inter-superoval contact or not. Furthermore, a finite difference method (FDM) is employed to numerically calculate the diffusivity of the composites. Finally, the reliability of GEMT-AEAF theoretical framework is validated by comparing with numerical results from FDM. (c) 2021 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据