4.7 Article

Embedded carbon nanotubes on surface of thermoplastic poly(ether ether ketone)

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POLYMER
卷 226, 期 -, 页码 -

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ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2021.123807

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Carbon nanotubes; PEEK; Nanocomposite; Raman spectroscopy; TEM

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The conductivity of thermoplastic polymers can be effectively enhanced by incorporating carbon nanotubes on the surface. Multiwall carbon nanotubes thin films were transferred onto the polymer surface to form composite layers with electrical conductivity up to 8 S/cm, showing variations at 2.8 vol% of nanotubes. The distribution and quantity of nanotubes were studied using transmission electron microscopy and optical transmission measurements.
The conductivity of thermoplastic polymers can be effectively enhanced by using conductive fillers on surfaces. Carbon nanotubes are incorporated in thermoplastic poly(ether ether ketone) polymer, a polymer that is used extensively in aerospace applications, by annealing of uniform carbon nanotubes thin films on the polymer surface. Multiwall carbon nanotubes thin films of 2 cm2 area was obtained by nanotube suspensions in methanol placed on water surface and then transferred on polymer surface. Single and multiple layers of nanotubes were deposited. The 200 nm thick composite layers so formed, showed an electrical conductivity up to 8 S/cm. Strong variations in the electronic transport was observed at 2.8 vol% of carbon nanotubes. The distribution of individual carbon nanotubes in the composite layer was studied by transmission electron microscopy. The amount of carbon nanotubes in the surface composite falling in the range of 2-12 vol% were determined through optical transmission measurements.

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