期刊
POLYMER
卷 231, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2021.124121
关键词
Ferroferric oxide; Poly(L-lactide); Nucleating agent
资金
- Natural Science Foundation Project of Chongqing [cstc2020jcyj-msxmX0401]
- Opening Project of Beijing Key Laboratory of Quality Evaluation Technology for Hygiene and Safety of Plastics (BeijingTechnology and Business University) [QETHSP2021002]
- Opening Project of State Key Laboratory of Polymer Materials Engineering (Sichuan University) [sklpme2020-4-10]
The study demonstrates that using magnetic nanoparticles as nucleating agents can effectively improve the crystallinity, gas barrier properties, thermal performance, and mechanical performance of PLLA, while maintaining high recyclability.
Herein, a recyclable nucleating agent for poly(L-lactide) (PLLA) was fabricated via taking advantage of grafting biodegradable poly(3-hydroxybutyrate)-diol onto the surface of magnetic nanoparticles (ferroferric oxide, Fe3O4). Its effectiveness in improving crystallinity, gas barriers, thermal, and mechanical performance of PLLA are investigated. Core-shell structure, which is the combination of PHB-diol (shell) and magnetic nanoparticle (core), are detected by means of transmission electron microscope. Differential scanning calorimeter results suggest Fe3O4@SiO2-PHB (MM) nanoparticles exert great potential in accelerating the crystallization rate. Besides, with the increment of crystallinity for PLLA matrix, oxygen permeability and water vapor permeability are reduced, while thermal stability and mechanical property increases. Most importantly, this magnetic nucleating agent can be recollected and re-manufactured into new batch of PLLA composites without losing the nucleation efficiency, which successfully keep consistent with recyclable and highly-efficient aspiration.
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