4.8 Article

Synthesis of 1,1-Diboryl Alkenes Using the Boryl-Heck Reaction

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ORGANIC LETTERS
卷 23, 期 12, 页码 4838-4842

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AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c01567

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资金

  1. University of Delaware
  2. National Science Foundation [CAREER CHE-1254360, CHE-1800011]
  3. NIH [NSF CHE-0421224, CHE-0840401, NIH S10OD01626 7, S10RR02696, P20GM104316, P30GM110758]

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The research reported a method for synthesizing 1,1-diboryl alkenes from terminal alkenes, showing 1,1-regioselective addition for both conjugated and unconjugated alkenes. This provides a single method to prepare a wide range of 1,1-diboryl alkenes.
The synthesis of 1,1-diboryl alkenes from terminal alkenes is reported. 1,1-Regioselective addition is observed for both conjugated and unconjugated alkenes, allowing for a single method to prepare a wide range of 1,1-diboryl alkenes.

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