4.8 Article

Photocatalytic C-H Trifluoromethylthiolation by the Decatungstate Anion

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Review Chemistry, Multidisciplinary

Radical-Promoted Distal C-H Functionalization of C(sp3) Centers with Fluorinated Moieties

Enzo Nobile et al.

Summary: Fluorinated scaffolds play a pivotal role in pharmaceuticals, agrochemicals, and materials science. Recent attention has focused on the development of versatile strategies for the selective synthesis of fluorinated molecules through direct C-H bond functionalization, particularly in designing novel transformations based on radical processes to introduce fluorinated groups.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Decatungstate as a direct hydrogen atom transfer photocatalyst for synthesis of trifluromethylthioesters from aldehydes

Xiaochen Wang et al.

Summary: A versatile and mild protocol for trifluoromethylthiolation reactions of aldehydes has been developed, catalyzed by a decatungstate hydrogen atom transfer photocatalyst under redox-neutral conditions. The protocol is highly selective, operationally simple, and compatible with a wide array of sensitive functional groups, making it convenient for late-stage functionalization of bioactive molecules in drug discovery.

CHINESE CHEMICAL LETTERS (2021)

Article Chemistry, Multidisciplinary

Trifluoromethyl Sulfoxides: Reagents for Metal-Free C-H Trifluoromethylthiolation

Dong Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Multidisciplinary Sciences

Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes

Hui Cao et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)-H trifluoromethylation

Patrick J. Sarver et al.

NATURE CHEMISTRY (2020)

Review Chemistry, Multidisciplinary

Generation of Alkyl Radicals: From the Tyranny of Tin to the Photon Democracy

Stefano Crespi et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Multidisciplinary

Remote Fluorination and Fluoroalkyl(thiol)ation Reactions

Fa-Guang Zhang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Article Multidisciplinary Sciences

C(sp3)-H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow

Gabriele Laudadio et al.

SCIENCE (2020)

Article Chemistry, Multidisciplinary

Formyl-selective deuteration of aldehydes with D2O via synergistic organic and photoredox catalysis

Jianyang Dong et al.

CHEMICAL SCIENCE (2020)

Review Chemistry, Multidisciplinary

Photocatalytic hydrogen atom transfer: the philosopher's stone for late-stage functionalization?

Luca Capaldo et al.

GREEN CHEMISTRY (2020)

Article Chemistry, Organic

Synthesis of trifluoromethylthioesters from aldehydes via a visible light-promoted radical process

Meng-Yue Wang et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Copper-Catalyzed, N-Directed Csp3-H Trifluoromethylthiolation (-SCF3) and Trifluoromethylselenation (-SeCF3)

Atanu Modak et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Multidisciplinary Sciences

Late-stage trifluoromethylthiolation of benzylic C-H bonds

Wentao Xu et al.

NATURE COMMUNICATIONS (2019)

Review Chemistry, Multidisciplinary

Merging Visible-Light Catalysis for the Direct Late-Stage Group-16-Trifluoromethyl Bond Formation

Clement Ghiazza et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

Article Chemistry, Multidisciplinary

Synergistic Catalysis for the Umpolung Trifluoromethylthiolation of Tertiary Ethers

Wentao Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Physical

Cooperative Catalysis: A Strategy To Synthesize Trifluoromethyl-thioesters from Aldehydes

Satobhisha Mukherjee et al.

ACS CATALYSIS (2018)

Article Chemistry, Multidisciplinary

Site-Selective Remote Radical C-H Functionalization of Unactivated C-H Bonds in Amides Using Sulfone Reagents

Yong Xia et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

Synthesis of acyl fluorides via photocatalytic fluorination of aldehydic C-H bonds

Michael Meanwell et al.

CHEMICAL COMMUNICATIONS (2018)

Article Multidisciplinary Sciences

Direct arylation of strong aliphatic C-H bonds

Ian B. Perry et al.

NATURE (2018)

Article Chemistry, Organic

Ag-Mediated Trifluoromethylthiolation of Inert Csp(3)-H Bond

Yue Zhao et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

Review Chemistry, Organic

Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis

Luca Capaldo et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2017)

Review Chemistry, Multidisciplinary

The Essential Role of Bond Energetics in C-H Activation/Functionalization

Xiao-Song Xue et al.

CHEMICAL REVIEWS (2017)

Review Chemistry, Multidisciplinary

Decatungstate Anion for Photocatalyzed Window Ledge Reactions

Davide Ravelli et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Review Chemistry, Multidisciplinary

State-of-the-Art in Electrophilic Trifluoromethylthiolation Reagents

Helene Chachignon et al.

CHINESE JOURNAL OF CHEMISTRY (2016)

Article Chemistry, Multidisciplinary

Visible-Light-Promoted Activation of Unactivated C(sp3)-H Bonds and Their Selective Trifluoromethylthiolation

Satobhisha Mukherjee et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Review Chemistry, Organic

Late stage trifluoromethylthiolation strategies for organic compounds

Sebastian Barata-Vallejo et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2016)

Article Chemistry, Multidisciplinary

Direct Trifluoromethylthiolation of Unactivated C(sp(3))-H Using Silver(I) Trifluoromethanethiolate and Potassium Persulfate

Hao Wu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Silver-Mediated Oxidative Aliphatic C-H Trifluoromethylthiolation

Shuo Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

A Convenient Photocatalytic Fluorination of Unactivated C-H Bonds

Shira D. Halperin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Review Chemistry, Medicinal

Trifluoromethyl Ethers and -Thioethers as Tools for Medicinal Chemistry and Drug Discovery

Gregory Landelle et al.

CURRENT TOPICS IN MEDICINAL CHEMISTRY (2014)

Review Chemistry, Organic

Direct Trifluoromethylthiolation Reactions: The Renaissance of an Old Concept

Fabien Toulgoat et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2014)

Article Chemistry, Multidisciplinary

Formation of CSCF3 Bonds through Direct Trifluoromethylthiolation

Anis Tlili et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Review Chemistry, Multidisciplinary

Introduction of Fluorine and Fluorine-Containing Functional Groups

Theresa Liang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Review Chemistry, Organic

Aromatic and heterocyclic perfluoroalkyl sulfides. Methods of preparation

Vladimir N. Boiko

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2010)

Review Chemistry, Multidisciplinary

Decatungstate as an efficient photocatalyst in organic chemistry

Manolis D. Tzirakis et al.

CHEMICAL SOCIETY REVIEWS (2009)

Review Chemistry, Multidisciplinary

The economies of synthesis

Timothy Newhouse et al.

CHEMICAL SOCIETY REVIEWS (2009)

Review Chemistry, Multidisciplinary

α-fluorinated ethers, thioethers, and amines:: Anomerically biased species

F Leroux et al.

CHEMICAL REVIEWS (2005)

Article Chemistry, Organic

Trifluoromethylsulfenylation of masked carbonyl compounds

S Munavalli et al.

SYNTHETIC COMMUNICATIONS (2000)