期刊
ORGANIC LETTERS
卷 23, 期 15, 页码 5942-5946出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c02039
关键词
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资金
- Research Grants Council of the Hong Kong Special Administrative Region [14324116, 18K05076]
- Japan Society for the Promotion of Science
A series of phenanthroline-fused phthalocyanine analogues with a 16 pi-electron skeleton were synthesized in this study, showing monovalent corrole inner perimeter and nonaromatic characteristics as revealed by their spectroscopic data and theoretical studies.
Condensation of 4,5- bis( 4- tert- butyl- 2,6-dimethylphenoxy)phthalonitrile with 2,9-diamino-1,10-phenanthroline in the presence of M(OAc)(2) (M = Ni, Pd, Zn) afforded a series of phenanthroline-fused phthalocyanine analogues with a 16 pi-electron skeleton. While the arrangement of elements along the inner perimeter of these macrocycles is the same as that of the hitherto reported trivalent corroles, they represent the first example of porphyrinoids possessing a monovalent corrole inner perimeter and nonaromatic characteristics as revealed by their spectroscopic data and theoretical studies.
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