期刊
OPTICS EXPRESS
卷 29, 期 21, 页码 32818-32825出版社
OPTICAL SOC AMER
DOI: 10.1364/OE.435835
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资金
- Natural Science Foundation of Hebei Province [A2020201028]
- Hebei University [HBU2021ss069]
In this paper, ARP Raman spectroscopy was used to investigate the polarization properties of E-2g(1) and A(1g) modes on different planes of 2H-MoS2 crystal. The results showed that the polarization properties of these modes depended on the polarization direction of the incident laser and the in-plane rotation of the sample. The experimental results were confirmed and analyzed through theoretical calculations, providing insights into the effect of atomic structure on ARP Raman properties in stacked MoS2 layers and offering a reference for studying other two-dimensional layered crystalline materials.
Angle-resolved polarized (ARP) Raman spectroscopy can be utilized to characterize the Raman modes of two-dimensional layered materials based on crystal symmetry or crystal orientation. In this paper, the polarization properties of E-2g(1) and A(1g) modes on the basal plane and edge plane of high purity 2H-MoS2 bulk crystal grown by chemical vapor transport (CVT) method were investigated by ARP Raman spectroscopy. The I and II type ARP Raman spectroscopy with four kinds of polarization configurations: alpha Y, alpha X, beta Y, and beta X were used to explore the intensity dependence of E-2g(1) and A(1g) modes at different planes on the polarization direction of incident/scattered light. The results show that the E-2g(1) and A(1g) modes exhibit different polarization properties dependent on the polarization of the incident laser and the in-plane rotation of the sample at different planes. The experimental results were confirmed and analyzed through theoretical calculation. Our work sheds light on the intriguing effect of the subtle atomic structure in stacked MoS2 layers on the resulting ARP Raman properties. This provides a reference for the study of other two-dimensional layered crystalline materials by ARP Raman spectroscopy. (C) 2021 Optical Society of America under the terms of the OSA Open Access Publishing Agreement
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