Double-site defect passivation of perovskite film via fullerene additive engineering toward highly efficient and stable bulk heterojunction solar cells

Bulk heterojunction (BHJ) perovskite solar cells (PVKSCs) are advantageous in passivating defects and fa-cilitating electron extraction/transport. Most of the reported fullerene derivatives involved in BHJ-PVKSCs render single-site interactions, limiting their passivation effect. Herein, we developed a perfluoroalkyl and pyridine-cofunctionalized fullerene derivative (C-60-PyF15), and applied it as an additive of CH3NH3PbI3 layer to construct inverted (p-i-n) BHJ-PVKSCs, affording double-site defect passivation of perovskite film and a champion power conversion efficiency of 20.10%, which is among the highest values for fullerene-incorporated inverted BHJ-PVKSCs. To elucidate the crucial role of the perfluoroalkyl group in efficiency enhancement, another analogous novel non-fluoro-substituted pyridine-functionalized fullerene derivative with the same chain length of alkyl group (C-60-PyH15) was also synthesized, which afforded a champion PCE of 19.22% and is lower than that of C-60-PyF15. The double-site defect passivation ability of C-60-PyF15 is resulted from the coordination interaction of the pyridine moiety with Pb2+ ions and hydrogen bonding between the fluorine atom within the perfluoroalkyl group and the CH3NH3+ cations. These enable ordered orientation of CH3NH3+ and suppressed ion migration, leading to efficiency enhancement and improved ambient and thermal stabilities. (C) 2021 Elsevier Ltd. All rights reserved.

Automated summary

The study developed a novel perfluoroalkyl and pyridine-cofunctionalized fullerene derivative, which achieved double-site defect passivation of perovskite film and a champion power conversion efficiency of 20.10% for inverted BHJ-PVKSCs. Additional experiments with a non-fluoro-substituted pyridine-functionalized fullerene derivative demonstrated the crucial role of the perfluoroalkyl group in efficiency enhancement.