期刊
NANO RESEARCH
卷 15, 期 3, 页码 1809-1816出版社
TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-021-3755-7
关键词
electronic structure; interfacial S sites; d-band center; hydrogen evolution reaction
类别
资金
- National Natural Science Foundation of China [51871078, 52071119]
- Heilongjiang Science Foundation [E201808]
This study activated the interfacial S sites of MoS2 nanosheets by coupling with Ru nanoparticles on the inert basal plane, modulating the electronic structure and optimizing H adsorption. As a result, the Ru-MoS2 catalyst exhibited significantly improved hydrogen evolution reaction performance in both acidic and alkaline solutions, demonstrating the potential for enhancing the activity of other transition metal sulfide electrocatalysts.
The hydrogen evolution reaction (HER) of molybdenum disulfide (MoS2) is limited in alkaline and acid solution because the active sites are on the finite edge with extended basal plane remaining inert. Herein, we activated the interfacial S sites by coupling with Ru nanoparticles on the inert basal plane of MoS2 nanosheets. The density functional theory (DFT) calculation and experimental results show that the interfacial S electronic structure was modulated. And the results of Delta G(H*) demonstrate that the adsorption of H on the MoS2 was also optimized. With the advantage of interfacial S sites activation, the Ru-MoS2 needs only overpotential of 110 and 98 mV to achieve 10 mA center dot cm(-2) in both 0.5 M H2SO4 and 1 M KOH solution, respectively. This strategy paves a new way for activating the basal plane of other transition metal sulfide electrocatalysts for improving the HER performance.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据