期刊
NANO LETTERS
卷 21, 期 15, 页码 6425-6431出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.1c00773
关键词
GaN nanocrystals; nanoscale compression; plasticity; ultrahigh voltage electron microscopy; ab initio calculations; MD-simulations
类别
资金
- Panasonic Corp., Japan
- Nagaoka University of Technology
The research reveals that nanodeconfined GaN compressed along the M direction exhibits room-temperature plasticity, while the response along the C direction is quasi-brittle. First-principles bandgap calculations, nanomechanical tests, and ultrahigh-voltage transmission electron microscopy observations confirm the authenticity of the phenomenon. Molecular dynamics simulations demonstrate how this process occurs in C- and M-oriented GaN frustum, reflecting nanopillar crystals.
GaN wurtzite crystal is commonly regarded as eminently brittle. However, our research demonstrates that nanodeconfined GaN compressed along the M direction begins to exhibit room-temperature plasticity, yielding a dislocation-free structure despite the occurrence of considerable, irreversible deformation. Our interest in M-oriented, strained GaN nano-objects was sparked by the results of first-principles bandgap calculations, whereas subsequent nanomechanical tests and ultrahigh-voltage (1250 kV) transmission electron microscopy observations confirmed the authenticity of the phenomenon. Moreover, identical experiments along the C direction produced only a quasi-brittle response. Precisely how this happens is demonstrated by molecular dynamics simulations of the deformation of the C- and M-oriented GaN frustum, which mirror our nanopillar crystals.
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