期刊
MOLECULES
卷 26, 期 15, 页码 -出版社
MDPI
DOI: 10.3390/molecules26154687
关键词
polymeric catalysts; hydrogenation of arenes; noble metals; hyper-cross-linked polystyrene; catalyst stability
资金
- Russian Science Foundation [20-19-00386]
- Russian Science Foundation [20-19-00386] Funding Source: Russian Science Foundation
The study demonstrated that noble metal nanoparticles stabilized in hyper-cross-linked polystyrene effectively catalyzed the hydrogenation of various arenes in different medium and allowed for multiple catalyst reuses.
This work is addressing the arenes' hydrogenation-the processes of high importance for petrochemical, chemical and pharmaceutical industries. Noble metal (Pd, Pt, Ru) nanoparticles (NPs) stabilized in hyper-cross-linked polystyrene (HPS) were shown to be active and selective catalysts in hydrogenation of a wide range of arenes (monocyclic, condensed, substituted, etc.) in a batch mode. HPS effectively stabilized metal NPs during hydrogenation in different medium (water, organic solvents) and allowed multiple catalyst reuses.
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