期刊
MICROCHEMICAL JOURNAL
卷 165, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.microc.2021.106171
关键词
Carbon ceramic electrode; Electrochemical sensors; Hydrazine; Nanomaterials; Cobalt oxide
资金
- Ministry of Higher Education of the Kingdom of Saudi Arabia
- Deanship of Scientific Research at Najran University [NU/ESCI/17/110]
An electrochemical sensor for hydrazine detection in wastewater was successfully developed using Co3O4 nanoparticles and mesoporous SiO2/C composite, showing high sensitivity, rapid response, stability, and repeatability.
An electrochemical sensor was developed for hydrazine detection in wastewater. Cobalt oxide (Co3O4) nanoparticles were in-situ synthesized in the pores and distributed uniformly within the prepared mesoporous SiO2/C. The mesoporous composite has a high surface area (SBET 432.56 m2?g- 1), a bigger volume of pores (0.89 cm3?g- 1), and pore size of about 7?8 nm, evaluated by BET methodology. SEM images and the corresponding elemental mapping have shown no phase segregation at the applied magnification. The prepared composite Co3O4@SiO2/C was compressed in disk shape to make a working electrode for electrochemical hydrazine detection at pH 7. The limit of detection, the limit of quantification, linear response range, and sensitivity are 0.08 ?M, 0.1x10-6 M, 10?1800 ?M, and 430 ?A??M cm-2, respectively. The sensor response time in the presence of hydrazine at 100 ?M is less than 2 s. The sensing probe exhibited chemical stability, high sensitivity, and negligible interference with other electroactive species found in river water and industrial effluents. The sensor?s repeatability was measured as 1.97% (RSD; for n = 10 at 600 ?M hydrazine level).
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