4.3 Article

Binary nanocomposites of reduced graphene oxide and cobalt (II, III) oxide for supercapacitor devices

期刊

MATERIALS TECHNOLOGY
卷 37, 期 9, 页码 1168-1182

出版社

TAYLOR & FRANCIS LTD
DOI: 10.1080/10667857.2021.1926810

关键词

Supercapacitor; Co3O4; energy density; nanocomposite; reduced graphene oxide

资金

  1. project Trakya University, TUBAP [2018-138]

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In this study, a simple and cost-effective preparation method of rGO/Co3O4 nanocomposite was proposed. The electroactive materials were characterized by various techniques, and the nanocomposite showed excellent electrochemical performance at different monomer concentrations.
In this study, a simple and one-step cost-effective preparation of rGO/Co3O4 nanocomposite was given out in different monomer concentrations of [rGO]o/[Co3O4]o= 1:1; 1:2; 1:5 and 1:10. The electroactive materials were characterized by many techniques, such as FTIR-ATR, XPS, TGA-DTA, Raman, BET surface analysis, GCD, SEM-EDX, XRD, TEM, CV, and EIS analysis. A symmetric supercapacitor applying rGO/Co3O4 nanocomposite as positive and negative electrodes was taken in the potential window between 0.0 and 0.8 V as the highest specific capacitance of Csp= 115.35 Fxg-1 at 2 mVxs-1 for [rGO]o/[Co3O4]o= 1:2. Furthermore, the highest energy (E) and power densities (P) were obtained as E= 20.16 Whxkg-1 at 40 mA and P= 26.140 kWxkg-1 at 10 mA for [rGO]o/[Co3O4]o= 1:2 by GCD method, respectively. As a result, rGO/Co3O4 nanocomposite at different monomer concentrations showed an easy synthesis, a sustainable approach, and a high electrochemical performances for energy storage devices.

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