4.6 Article

Heated air sensitivity of Zn1-xCdxO films

期刊

MATERIALS RESEARCH BULLETIN
卷 138, 期 -, 页码 -

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2021.111213

关键词

Cd doped ZnO; Spray pyrolysis; Silicon substrate; Heat sensor

资金

  1. Fundacao de Amparo a Pesquisa do Estado de Sao Paulo - Fapesp [2016/10973-4]
  2. CNPq
  3. CAPES

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The heat sensitivity of Zn1-xCdxO films is found to be related to structural phase transition, with surface morphology dependent on substrate type and Cd concentration. Samples grown on Si substrates exhibit higher thermal sensitivity and signal quality, making the films suitable for practical applications within a strategic temperature range of 50-100 degrees C.
In this work, we have investigated the heat sensitivity of a Zn1-xCdxO (x= 0.03-1) films obtained by spraypyrolysis under the influence of atmospheric air, considering the substrate type, air temperature, and Cd concentration. We found a transition in the electrical conductivity behavior when x is around 0.55 (55 at.% Cd). This transition is related to the structural phase transition that also occurs close to this concentration. It has been proved that the thermal response amplitude is directly related to the surface morphology of films, which depends on the substrate type and the Cd concentration. We found that thermal sensitivity and signal quality are higher for samples grown on top of Si substrates. The conductivity changes are reproducible over a strategic temperature range (50-100 degrees C), making the films available for practical applications.

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