期刊
MATERIALS LETTERS
卷 293, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.matlet.2021.129712
关键词
Energy storage and conversion; Composite materials; Porous material; Si anode; Conductive polymer
资金
- National Natural Science Foun-dation of China [21905087]
- Undergraduates Innovative Train-ing Foundation of Central South University [GCX2020341Y]
- Hunan Provincial Science and Technology Plan Project, China [2017TP1001]
- Hunan Provincial Natural Science Foundation of China [2020JJ4107]
- Innovation-Driven Project of Central South University [2020CX037]
By coating poly (3, 4-ethylenedioxythiophene) (PEDOT) on the surface of micro-Si, a porous micro-Si anode was successfully synthesized with excellent performance in lithium ion batteries. The synergistic effect of porous structure and PEDOT protective layer not only helps alleviate volume expansion of silicon, but also enhances its conductivity. This study provides an attractive strategy to address volume expansion and low conductivity issues in silicon anodes, which is significant for the development of high energy density LIBs.
To address the serious volume expansion and poor conductivity of silicon anode in lithium ion batteries (LIBs), a strategy through coating conductive polymer on the surface of micro-Si via a facile wet chemical process is proposed. In this way, a porous micro-Si anode coated with poly (3, 4-ethylenedioxythiophene) (PEDOT) was synthesized. This material shows a capacity as high as 1168 mAh g(-1) at high current rate of 2000 mA g(-1) for anode of LIBs. The synergistic effect of porous structure and PEDOT protective layer could not only relieve the volume expansion, but also enhance the conductivity of Si. This study provides an attractive strategy to deal with volume expansion and low conductivity of Si, which could be very meaningful for the development of high energy density LIBs. (C) 2021 Elsevier B.V. All rights reserved.
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