4.6 Article

HPAMAM/PMMA composite electrospun film for cobalt ion detection in water environments

期刊

MATERIALS LETTERS
卷 299, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.matlet.2021.130115

关键词

Luminescence; Metal ion; Sensors; Poly(amido amine); Electrospun

资金

  1. Natural Science Foundation of Anhui Province [1808085ME112]
  2. Fundamental Research Funds for the Central Universities of China [PA2020GDSK0066]
  3. Key Lab of Photovoltaic and Energy Conservation Materials, Chinese Academy of Sciences

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A film-type detector was fabricated from hyperbranched fluorescent poly(amido amine) (HPAMAM) and polymethyl methacrylate (PMMA) through electrospinning to detect cobalt ion in aqueous solution with high sensitivity and selectivity. The fluorescence quenching obeys the Stern-Volmer law in a linear range of 1-50 mu M, providing an effective route to fabricate film-type detectors from nonconjugated fluorescent polymers.
Nonconjugated fluorescent polymers are an important class of fluorescent materials for the detection of heavy metal ions. However, the utilization of nonconjugated fluorescent polymer to fabricate film-type detector is mostly limited due to their branched molecular structure. Here in this article, a film-type detector from hyperbranched fluorescent poly(amido amine) (HPAMAM) and polymethyl methacrylate (PMMA) was fabricated through electrospinning to detect cobalt ion in aqueous solution. The HPAMAM/PMMA composite film can respond to Co2+ ions with high sensitivity and selectivity. Moreover, the fluorescence quenching obeys the Stern-Volmer law in a linear range of 1-50 mu M. This work provides an effective route to fabricate film-type detectors from nonconjugated fluorescent polymers. (C) 2021 Elsevier B.V. All rights reserved.

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