4.6 Article

Effect of heat treatment on WO3 nanostructures based NO2 gas sensor low-cost device

期刊

MATERIALS CHEMISTRY AND PHYSICS
卷 269, 期 -, 页码 -

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.matchemphys.2021.124731

关键词

WO3; NO2; Sensor; Pulsed laser technique; Heat treatment

资金

  1. Mustansiriyah University, Baghdad-Iraq

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This study investigated the heat treatment influence on the morphological, structural, and gas sensing performance of Tungsten trioxide, and observed optimal crystalline size and surface area at 750 degrees C. The surface morphology of Tungsten trioxide showed a grape-like structure with high surface roughness, making it active for gas molecules. Furthermore, WO3 nano-structures demonstrated high selectivity, stability, and reproducibility to NO2 toxic gas.
This study introduces an elaboration of the heat treatment influence on the morphological, structural, and gas sensing performance of Tungsten trioxide. It has been coated by pulsed laser technique (PLT) using optimized conditions. The optimum crystalline size and surface area have been observed at (750 degrees C) of heat treatment with values of 47.81 nm and 20.45 m(2)/g, respectively. The surface morphology of Tungsten trioxide depicted that the shape of film has bunches of grapes-like structure with a high number of pores which is the perfect one for the sensing performance. The higher surface roughness investigated by AFM makes it more active for the gas molecules. The electronic structure analysis confirmed the presence of oxygen vacancies which provide a lot of sites for the gas molecules. The gas-sensing performance towards the (NO2) molecules has been measured, and it was found that the film sensor revealed an ultra-gas response at the room temperature with a value of (392%) for the gas concentration of (150) ppm. Furthermore, the limit of detection manifested that the device can detect the minimum value concentration of (1.72 ppm) NO2 gas molecules at the room temperature. Besides, WO3 nano-structures have high selectivity, stability, and reproducibility to the NO2 toxic gas.

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