期刊
MACROMOLECULES
卷 54, 期 11, 页码 5043-5052出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.1c00563
关键词
-
资金
- National Natural Science Foundation of China [51973011, 21774009, 52003022]
- China Postdoctoral Science Foundation [2019TQ0022, 2020M670111]
- Major Scientific and Technological Innovation Project in Shandong Province [2019JZZY020218]
- Fundamental Research Funds for the Central Universities [XK1802-2]
This study successfully controlled the handedness and magnitude of circularly polarized luminescence (CPL) by synthesizing chiral helical polyacetylenes and observing CPL inversion and amplification in thin solid films. Changing the film-forming solvents can regulate the CPL values of the films, providing a new strategy for constructing CPL materials with tunable handedness and a large dissymmetry factor.
Precisely and conveniently controlling the handedness and magnitude of circularly polarized luminescence (CPL) is a key issue in developing CPL-active materials. In this work, a series of chiral helical polyacetylenes bearing pendant pyrene groups were synthesized. CPL inversion occurred when the polymer solutions fabricated into thin solid films. More interestingly, amplification of CPL was also observed during this process; that is, the polymer solution showed a luminescence dissymmetry factor (g(lum)) of 1 x 10(-3), while over 100-fold magnitude amplification of g(lum) values is obtained in the polymer films. Significantly, the g(lum) values of the films can be regulated from 10(-1) to 10(-3) by simply changing the film-forming solvents. The cause of the above phenomena is due to the presence of two different chirality transfer channels: intermolecular interactions in the solutions and the matching rule in the films. This study provides a new strategy to construct CPL materials with tunable handedness and a large dissymmetry factor.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据