期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 42, 期 23, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202100498
关键词
blends of polymers; nonlinear architecture; polymerization-induced self-assembly; poor polymerization control
资金
- National Natural Science Foundation of China [22171055, 21971047]
- Innovation Project of Education Department in Guangdong [2018KTSCX053]
- Guangdong Special Support Program [2017TX04N371]
This review discusses the recent advancements in polymerization-induced self-assembly (PISA), highlighting the expansion of methods including synthesis of nonlinear block copolymers, in situ synthesis of polymer blends, and utilization of macro-CTAs with low chain transfer constants. These examples provide new insights into PISA research and demonstrate the potential impact of these methods on polymer and colloid synthesis in the future.
Over the past decade or so, polymerization-induced self-assembly (PISA) has become a versatile method for rational preparation of concentrated block copolymer nanoparticles with a diverse set of morphologies. Much of the PISA literature has focused on the preparation of well-defined linear block copolymers by using linear macromolecular chain transfer agents (macro-CTAs) with high chain transfer constants. In this review, a recent process is highlighted from an unusual angle that has expanded the scope of PISA including i) synthesis of block copolymers with nonlinear architectures (e.g., star block copolymer, branched block copolymer) by PISA, ii) in situ synthesis of blends of polymers by PISA, and iii) utilization of macro-CTAs with low chain transfer constants in PISA. By highlighting these important examples, new insights into the research of PISA and future impact these methods will have on polymer and colloid synthesis are provided.
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