期刊
MACROMOLECULAR RAPID COMMUNICATIONS
卷 42, 期 15, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202100221
关键词
controlled polymerization; metal-free polymerization; O-ATRP; organic synthesis; photocatalysts
资金
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) [306464/2016-0, 423833/2018-9]
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES) [001]
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [18/02508-5]
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [18/02508-5] Funding Source: FAPESP
Reversible deactivation radical polymerization (RDRP) is a powerful technique for synthesizing polymers with well-defined properties. O-ATRP, an alternative to traditional ATRP, utilizes organic compounds as catalysts under light irradiation, allowing for the synthesis of advanced materials. Studies on the mechanism and applications of O-ATRP demonstrate its significant potential and impact in the synthesis of functional materials.
Reversible deactivation radical polymerization (RDRP) is a class of powerful techniques capable of synthesizing polymers with a well-defined structure, properties, and functionalities. Among the available RDRPs, ATRP is the most investigated. However, the necessity of a metal catalyst represents a drawback and limits its use for some applications. O-ATRP emerged as an alternative to traditional ATRP that uses organic compounds that catalyze polymerization under light irradiation instead of metal. The friendly nature and the robustness of O-ATRP allow its use in the synthesis of tailorable advanced materials with unique properties. In this review, the fundamental aspects of the reductive and oxidative quenching mechanism of O-ATRP are provided, as well as insights into each component and its role in the reaction. Besides, the breakthrough recent studies that applied O-ATRP for the synthesis of functional materials are presented, which illustrate the significant potential and impact of this technique across diverse fields.
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