Rheology of α-Gel Formed by Amino Acid-Based Surfactant with Long-Chain Alcohol: Effects of Inorganic Salt Concentration

Mixtures of surfactants, long-chain alcohols, and water sometimes yield lamellar gels with hexagonally packed alkyl chains. This assembly is called alpha-gel or alpha-form hydrated crystal. In this study, we characterized the rheological properties of alpha-gel prepared using disodium N-dodecanoylglutamate (C12Glu-2Na), 1-hexadecanol (Cl6OH), and water at different NaCI concentrations. The alpha-gel structure was assessed using small- and wide-angle X-ray scattering (SWAXS). The SWAXS measurements revealed that an increased NaCl concentration (0-200 mmol dm(-3)) resulted in a decreased d-spacing caused by the screening of electrostatic repulsion between lamellar bilayers. This led to an increased amount of excess water (i.e., the water present between the alpha-gel domains), and hence, the viscosity of the alpha-gel decreased in the range of the NaCl concentration. A further increase in the NaCl concentration (200-1000 mmol dm(-3)) resulted in decreased electrostatic repulsion between the alpha-gel domains and/or an increased number of alpha-gel domains (multilamellar vesicles). These effects increased the domain-to-domain interactions, leading to increased viscosity. Therefore, we concluded that the viscosity of the alpha-gel was controlled by the amount of excess water and the domain-to-domain interactions. Once the network structure collapsed under the strain, it was difficult to recover the original network structure. The low recoverability resulted from increased cohesion between the domains at high NaCl concentrations.

Automated summary

Increasing NaCl concentration reduced the spacing of alpha-gel, resulting in decreased viscosity; further increasing NaCl concentration increased domain interactions, leading to increased viscosity.