Surface Tension of the Oxide Skin of Gallium-Based Liquid Metals

Gallium-based alloys have garnered considerable attention in the scientific community, particularly as they are in an atypical liquid state at and near room temperature. Though physical parameters, such as thermal conductivity, electrical conductivity, viscosity, yield stress, and surface tension, of these alloys are broadly known, the surface tension (surface free energy) of the oxide skin remains intangible due to the high yield stress of the oxide skin. In this article, we propose to employ gradually attenuated vibrations to obtain equilibrium shapes, which are analyzed along the lines of the puddle height method. The surface tension of the oxide skin was determined on quartz glass and liquid metal-phobic diamond coating to be around 350-365 mN/m, thus independent of the substrate surface or employed liquid metal (i.e., eutectic Ga-In (EGaIn) and galinstan). The similarity of the surface tension for different alloys was ascribed to the composition of the oxide skin, which predominantly comprises gallium oxides due to thermodynamic constraints. We envision that this method can also be applied to other liquid metal alloys and liquid metal marble systems facilitating modeling, simulation, and optimization processes.

Automated summary

This article explores the surface tension of gallium-based alloys, determining it to be independent of substrate surface or liquid metal used. By using gradually attenuated vibrations and the puddle height method, the researchers were able to analyze equilibrium shapes and attribute the similarity of surface tension among different alloys to the composition of the oxide skin. The findings suggest potential application of this method to other liquid metal alloys and systems for modeling, simulation, and optimization processes.