4.7 Article

Blistering phenomenon of molten glass in contact with zirconia-based refractories

期刊

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 41, 期 10, 页码 5359-5366

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2021.03.063

关键词

Blistering; Oxygen semipermeation; Refractories; Zirconia percolation; Redox state

资金

  1. Saint-Gobain Research Provence, France

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This study aims to define the key parameters and propose a mechanism for blistering of soda-lime-silica glass melts in contact with fused-cast zirconia-based refractories, highlighting the roles of oxygen semipermeability through the zirconia skeleton and temperature.
The contact between a glass melt and some refractories in glass industry is able to induce a blistering phenomenon, which is detrimental for obtaining high quality glasses. The objective of this study is to define the key parameters of the blistering process and to propose a mechanism for blistering of soda-lime-silica glass melts in contact with fused-cast zirconia-based refractories. The roles of oxygen semipermeability through the zirconia skeleton and of temperature are emphasized.

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