期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 143, 期 27, 页码 10309-10316出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.1c03930
关键词
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资金
- National Natural Science Foundation of China [51890862, U1605245, 21975255, 21921001, 51902055]
- National Key Research and Development Plan of Ministry of Science and Technology [2016YFB0402104]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
By applying a rigidity-flexibility coupling strategy, a quaternary diamond-like phosphide, Mg2In3Si2P7, was designed and synthesized successfully, achieving the rare coexistence of giant second-harmonic generation, suitable band gap, moderate birefringence, and wide IR transparent range. This work not only opens a new avenue for designing advanced infrared nonlinear optical materials but also may spur more explorations on quaternary diamond-like pnictides.
Balancing the second-harmonic generation (SHG) coefficient, band gap, and birefringence is a vital but addressable challenge for designing infrared nonlinear optical materials. By applying a rigidity-flexibility coupling strategy, a quaternary diamond-like phosphide, Mg2In3Si2P7, with wurtzite-type superstructure was successfully designed and synthesized. Remarkably, it achieved the rare coexistence of giant second-harmonic generation (2 x ZnGeP2 and 7.1 x AgGaS2), suitable band gap (2.21 eV), moderate birefringence (0.107), and wide IR transparent range (0.56-16.4 mu m). First-principles calculations revealed that the giant SHG response and large birefringence can be attributed to the synergy of arrangement-aligned [InP4] and [SiP4] tetrahedra. This work not only opens a new avenue for designing advanced infrared nonlinear optical materials but also may spur more explorations on quaternary diamond-like pnictides.
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