期刊
JOURNAL OF SOLUTION CHEMISTRY
卷 50, 期 8, 页码 1124-1128出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10953-021-01111-5
关键词
Electrolyte solutions; Static permittivity; Langevin function; Nonlinear decrement; Extended Debye-Huckel theory
资金
- Russian Foundation for Basic Research [19-03-00033]
- IGIC RAS state assignment
- [121031300090-2]
The article discusses the nonlinear decrement of static permittivity of electrolyte solutions and the use of the Langevin function in the EDH theory. It also rebuts some statements made by Le and Tran.
In a recent article [J. Solution Chem. 50, 105 (2021)], Le and Tran discussed the nonlinear decrement of static permittivity of electrolyte solutions described by the Langevin function and its role in predicting activity coefficients using the extended Debye-Huckel (EDH) theory [Shilov I.Yu., Lyashchenko A.K. J. Phys. Chem. B 119, 10087 (2015)]. In this comment, we consider the mathematical description of permittivity concentration dependence, rebut some statements made by Le and Tran and provide an example of employing the Langevin function in the EDH theory.
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