Flux-growth of Ce:LiY6O5(BO3)3 single crystals during the Czochralski pulling from nearly congruent Ce:Li6Y(BO3)3 and their optical properties

Ce:Li6Y(BO3)(3) (LYBO) is a promising thermal neutron scintillator that can be grown into bulk single crystals by the Czochralski method although it melts incongruently. This study achieves 1-inch Ce:LYBO, and demonstrates the collateral flux-growth of LiY6O5(BO3)(3) (LYOB) single crystals at the bottom of the crucible during the pulling of LYBO from a stoichiometric melt. Both LYBO and LYOB belong to monoclinic crystal system with the same space group. Thermal analysis shows that LYOB itself is more incongruent than LYBO, decomposing mainly into Y16.86B8O38 phase when heated up to 1500 degrees C. In contrast to the typical bluish emission of Ce-doped scintillators, like the case of Ce:LYBO, Ce:LYOB crystals exhibit a broad emission peaking in the orange wavelength region, as a result from an extraordinarily large Stokes shift. The ultrafast photoluminescence (PL) decay of Ce:LYOB is due to dominant non-radiative processes that also cause obvious luminescence quenching. This study reports for the first time high-quality Ce:LYOB single crystals, which are characterized in terms of single crystal diffraction, thermal analysis, optical transmittance, excitation and PL at room temperature, PL decay and Raman spectroscopy.

Automated summary

LYBO and LYOB both belong to the monoclinic crystal system with the same space group. Ce:LYOB crystals exhibit broad emission in the orange wavelength region due to an extraordinarily large Stokes shift.