期刊
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER
卷 269, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jqsrt.2021.107650
关键词
Excitation energies; Wavelengths; Second-order many-body perturbation; theory; Multi-configuration Dirac-Hartree-Fock; method; Highly charged tungsten ions
资金
- National Natural Science Foundation of China [12074081, 11974080, 11703004]
- Nature Science Foundation of Hebei Province, China [A2019201300]
- Belgian FWO AMP
- FNRS Excellence of Science Programme [EOSO022818F]
- Swedish research council [2015-04842, 2016-04185]
- Fudan University
- Vinnova [2016-04185] Funding Source: Vinnova
The atomic properties of n = 3 states of W 56+ and W 61+ ions were systematically investigated using two state-of-the-art methods. The results achieved spectroscopic accuracy and will serve as a benchmark test for other theoretical calculations. This study will assist spectroscopists in identifying complex spectral lines.
Atomic properties of n = 3 states of the W 56+ W 61+ ions are systematically investigated through two state-of-the-art methods, namely, the second-order many-body perturbation theory, and the multi configuration Dirac-Hartree-Fock method combined with the relativistic configuration interaction approach. The contributions of valence-valence and core-valence electron correlations, the Breit interaction, the higher-order retardation correction beyond the Breit interaction through the transverse photon interaction, and the quantum electrodynamical corrections to the excitation energies are studied in detail. The excitation energies and wavelengths obtained with the two methods agree with each other within approximate to 0 . 01 %. The present results achieve spectroscopic accuracy and provide a benchmark test for various applications and other theoretical calculations of W 56+ W 61+ ions. They will assist spectroscopists in their assignment and direct identification of observed lines in complex spectra. (c) 2021 Elsevier Ltd. All rights reserved.
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