Oxygen-Enriched α-MoO3-x nanobelts suppress lithium dendrite formation in stable lithium-metal batteries

In this study, MoO3 nanobelts (MNBs) are passivated on lithium (Li) metal anodes to suppress Li dendrite formation and, thereby improve the stability in Li-metal batteries. MoO3 powder is ground into MNBs using a commercially viable mechanical grinding technique. The MNBs are then coated on Li metal using a simple spray-coating technique. The MNBs on top of the pristine Li mitigates the formation of Li dendrites by generating a uniform Li+ ion flux and providing shorter diffusion pathways. This facile passivation strategy prevents the growth of undesirable dendrites on pristine Li surfaces. A live transparent Li-Li symmetrical cell having MoO3-coated Li anode (MNB-Li) does not form any Li dendrites and undergoes minimal surface degradation relative to that of the corresponding pristine Li cell. The Li-Li symmetrical cells featuring the MoO3-coated surface operate with a low overpotential of approximately 18 mV for an extremely long period of time (ca. 2500 h) at a current density of 1 mA cm(-2). A Li-sulfur battery featuring the MNB-Li at 0.5 C significantly improves stability, with an initial capacity of 1127 mAh g(-1), a capacity of 820 mAh g(-1) for up to 200 cycles, and an excellent coulombic efficiency of 98.12 %.

Automated summary

In this study, MoO3 nanobelts were used to passivate Li metal anodes, effectively suppressing the formation of Li dendrites and improving stability. The MoO3-coated Li anode exhibited minimal surface degradation and low overpotential in symmetrical cells, showing promising potential for long cycle life and high coulombic efficiency in Li-metal batteries.