期刊
JOURNAL OF POWER SOURCES
卷 506, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2021.230074
关键词
Sb2O3; Catalytic; Alloying-conversion action; Coulombic efficiency; LIBs/NIBs
资金
- Scientific and Technological Developing Project of Jilin Province [20200401031GX, YDZJ202101ZYTS185]
- National Natural Science Foundation of China [21975250, 11902144]
- National Key R&D Program of China [2017YFE0198100]
- Open Project Program of Key Laboratory of Preparation and Application of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, China [2020005]
- Open Program of State Key Laboratory of Metastable Materials Science and Technology (Yanshan University), China [202110]
- High Performance Computing Center of Nanjing Tech University
By regulating the preparation of Sb2O3-Fe-C ternary composites, an optimized SFC-2 sample with excellent electrochemical performance as an anode material for alkali metal-ion batteries is achieved. The co-existence of Fe and conductive carbon in the SFC-2 electrode enables outstanding electrocatalytic effects, accelerating the transfer of alkali metal ions and redox reactions. The DFT calculation results demonstrate that Fe acts as a catalyst, improving initial Coulombic efficiencies and resulting in a high specific capacity and ICE for lithium and sodium ion batteries.
Herein, an optimized SFC-2 sample with excellent electrochemical performances as anode material for alkali metal-ion batteries via regulating a series of ternary composites of Sb2O3-Fe-C (SFC) prepared by ball milling is achieved. Due to the co-existence of Fe (20 wt%) and conductive carbon (10 wt%), the SFC-2 electrode exhibits outstanding electrocatalytic effects, which can make the alkaline metal ions transfer fast and accelerate the redox reactions. DFT calculation results further demonstrate Fe acting as a catalyst, which can catalyze the breaking of Sb-O bonds and Li-O bonds and reduce their binding energy, thus improving initial Coulombic efficiencies (ICEs) of the materials. As a result, the SFC-2 electrode releases a high specific capacity of 919 mA h g(-1) with a high ICE of 83.8% at 0.5 A g(-1) for lithium ion batteries (LIBs), which also has excellent electrochemical performances for sodium ion batteries (SIBs).
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