New CeO2-TiO2, WO3-TiO2 and WO3-CeO2-TiO2 mesoporous aerogel catalysts for the low temperature selective catalytic reduction of NO by NH3

New mesoporous and well-structured aerogel catalysts (CeO2-TiO2, WO3-TiO2 and WO3-CeO2-TiO2) were elaborated via the sol-gel method, characterized by means of various techniques (XRD; N-2-Physisorption at 77 K; NH3-TPD; H-2-TPR; DRUV-Vis spectroscopy) and evaluated in the selective catalytic reduction (SCR) of NO by NH3. The results reveal that all the aerogel catalysts develop essentially the diffraction peaks of TiO2 anatase phase and are classified as mesoporous materials with a high surface area (70 < S-BET < 106 m(2) g(-1)), large porosity (0.27 < V-PT < 0.46 cm(3) g(-1)) and nanometer size of crystallites (8-15 nm). The addition of Ce and/or W influences differently the structure, texture, crystallites size, surface oxygen concentration, total acidity and redox ability of aerogel samples and clearly affects their NO-SCR activity which follows this order: TiO2 < WO3-TiO2 < CeO2-TiO2 < WO3-CeO2-TiO2. It was also found that cerium species are more active in the low temperature NO-SCR reaction than tungsten ones (NO conversions obtained at 300 degrees C using CeO2-TiO2 and WO3-TiO2 were 75 and 0%, respectively). On the other hand, it was suggested that the interactions between Ce and W species play a key role in improving the reactivity of WO3-CeO2-TiO2 catalyst in the SCR of NO by NH3. Interestingly, the NO conversion into N-2 reaches 85% at 300 degrees C and exceeds 90% between 320 and 400 degrees C over this novel meso-structured aerogel catalyst.

Automated summary

The addition of Ce and/or W influences differently the structure, texture, crystallites size, surface oxygen concentration, total acidity and redox ability of aerogel samples and clearly affects their NO-SCR activity. It was found that cerium species are more active in the low temperature NO-SCR reaction than tungsten ones, and the NO conversion into N-2 reaches 85% at 300 degrees C and exceeds 90% between 320 and 400 degrees C over the WO3-CeO2-TiO2 catalyst.