4.6 Article

Si sputtering yield amplification: a study of the collisions cascade and species in the sputtering plasma

期刊

出版社

IOP PUBLISHING LTD
DOI: 10.1088/1361-6463/ac0c4e

关键词

sputtering; thin films; sputtering yield amplification; optical emission spectroscopy

资金

  1. National Council of Science, and Technology of Mexico, CONACyT [CB-2015-255156]
  2. PAPIIT-UNAM [IN112918, IG101220]
  3. CONACyT

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By doping a sputtering target with atoms of higher atomic mass, the sputtering yield amplification (SYA) phenomenon can be achieved, promoting a higher ejection of target atoms. A new method of generating the SYA phenomenon without the need for expensive and complex deposition systems was presented by increasing working pressure and adding dopant elements. Experimental results showed that the percentage of SYA depends on the number of redeposited dopant atoms and their depth distribution on the target surface.
The sputtering yield amplification (SYA) is a phenomenon based on doping a sputtering target with atoms of higher atomic mass. This doping changes the depth and the direction of the collision cascade in the target surface promoting a higher ejection of target atoms. In this work, we present a new way of generating the SYA phenomenon without the need of expensive and complex deposition systems. This was accomplished by increasing the working pressure and adding small pieces of W, as dopant element, on the racetrack of a Si target. The physical phenomena necessary to promote the SYA, for our experimental parameters, were analysed in two different deposition chambers and two sizes of sputtering targets. Based on the collisions in the gas phase, a calculation on the number of W atoms returning to the racetrack area was made, considering the number of atoms deposited on the thin films, to determine their effect on the cascade of collisions. In addition, calculations with the simulation of metal transport code were developed to determine the location on the racetrack zone the returning atoms were redeposited. By using reference samples placed on the racetrack of the Si target, we found that the percentage of SYA depends on the number of dopant atoms redeposited as well as the depth distribution these atoms had in the racetrack surface.

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