Non-π-Conjugated Deep-Ultraviolet Nonlinear Optical Crystal K2Zn3(SO4)(HSO4)2F4

Deep-ultraviolet (deep-UV) (wavelengths of <200 nm) nonlinear optical (NLO) materials are playing an increasingly important role because of their significant technological applications in advanced scientific instruments. In recent years, the non-pconjugated systems have received extensive attention as new emerging sources of deep-UV NLO materials. Here, a new non-pi-conjugated deep-UV NLO material, K2Zn3(SO4)-(HSO4)(2)F-4, has been successfully obtained by the hydrothermal method. It has a layered structure formed by [Zn-3(SO4)(HSO4)(2)F-3](infinity) layers bridged via K-O and K-F bonds. Powder second-harmonic generation shows that K2Zn3(SO4)(HSO4)(2)F-4 can achieve phase matching, and the response is similar to 0.3 times that of KH2PO4. Remarkably, the single-crystal transmittance spectrum confirms that the absorption edge of K2Zn3(SO4)(HSO4)(2)F-4 is below 200 nm, and the experimentally measured birefringence is 0.0126 at lambda = 546 nm. Indepth first-principles calculations illustrate well the microscopic origin of the optical properties. This work enriches the structrual diversity of non-pi-conjugated deep-UV NLO materials.

Automated summary

A new non-pi-conjugated deep-UV NLO material, K2Zn3(SO4)(HSO4)(2)F-4, has been successfully obtained by the hydrothermal method. It shows good phase matching properties and lower absorption edge, with a birefringence of 0.0126.