期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 86, 期 17, 页码 12277-12284出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c00562
关键词
-
资金
- DST-SERB, New Delhi, India [PDF/2018/000072]
- SERB, New Delhi, India, [CRG/2018/004424]
The new method reported in this study synthesizes 1,2,3-triazole-fused polyaromatic frameworks through a three-step reaction. Under mild conditions, the target products are obtained, along with the corresponding dihydrocarbocycles.
The 1,2,3-triazole-fused polyaromatic frameworks are traditionally obtained through transition metal-catalyzed C-H/C-X arylation of the preinstalled triazoles at a very high temperature. Herein, a transition metal-free direct synthesis via an aryne Diels-Alder/1,3-prototropic shift/dehydrobromination cascade is reported. This method gives access to triazole-fused aromatics as well as the corresponding dihydrocarbocycles under mild reaction conditions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据