期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 86, 期 12, 页码 8402-8413出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c00838
关键词
-
资金
- National Natural Science Foundation of China [21871253, 21672209]
Functionalized 1,3-dienes were efficiently accessed through palladium-catalyzed Heck reaction under mild conditions, showcasing tolerance of various functional groups and further transformation potential to highly functionalized trisubstituted furan derivatives.
Functionalized 1,3-dienes were efficiently accessed from visible-light-driven, palladium-catalyzed Heck reaction of S,S-functionalized internal vinyl bromides with styrenes under mild conditions. This Heck reaction showcased tolerance of a wide array of functional groups, afforded the target products in moderate to excellent yields through a radical reaction pathway. The resultant diene products could be further transformed to highly functionalized trisubstituted furan derivatives.
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