期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 86, 期 12, 页码 8295-8307出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c00746
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资金
- Italian Ministry of Research
- Huvepharma srl
- Regione Piemonte
- Cassa di Risparmio di Torino
The reactivity of furan-ynes in combination with pyridine and quinoline N-oxides in the presence of a Au(I) catalyst has been studied, enabling the synthesis of three different heterocyclic scaffolds. Selective access to two out of the three possible products has been achieved through the fine-tuning of the reaction conditions. The reactions proceed smoothly at room temperature and open-air, and were further extended to a broad substrate scope, affording functionalized dihydropyridinones and pyranones.
The reactivity of furan-ynes in combination with pyridine and quinoline N-oxides in the presence of a Au(I) catalyst, has been studied, enabling the synthesis of three different heterocyclic scaffolds. Selective access to two out of the three possible products, a dihydropyridinone and a furan enone, has been achieved through the fine-tuning of the reaction conditions. The reactions proceed smoothly at room temperature and open-air, and were further extended to a broad substrate scope, thus affording functionalized dihydropyridinones and pyranones.
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