期刊
JOURNAL OF MOLECULAR LIQUIDS
卷 345, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molliq.2021.117032
关键词
Schiff base; HCl medium; Mild steel; Corrosion inhibition; Langmuir adsorption isotherm; DFT calculation
资金
- Open Fund Project of Sichuan Province Key Laboratory of Comprehensive Utilization of Vanadium and Titanium Resources [2018FTSZ09]
- Open Fund Project of Key Laboratory of Materials Corrosion and Protection of Sichuan Province [2016CL02]
- Science and Technology Bureau of Zigong City [2019CXMZ01, 2020MZGC06]
- Graduate Innovation Fund Project of Sichuan University of Science and Technology [y2020040, y2020076, y2021002]
- Training Program of Innovation and Entrepreneurship for Undergraduates of Sichuan University of Science and Technology [cx2019198]
A new rigid double Schiff base of PBPM was synthesized and evaluated as a corrosion inhibitor for mild steel in 1.0 mol L-1 HCl medium. The results showed that PBPM exhibited high inhibition efficiency and acted as a mixed-type corrosion inhibitor. The adsorption of PBPM on mild steel surfaces followed Langmuir adsorption isotherm, and a protective film was formed. DFT calculations and Fukui functions revealed the influence of PBPM's molecular configuration on its corrosion inhibition behavior.
A new rigid double Schiff base of N,N'-(1,3-phenylene)bis(1-(pyridin-2-yl)methanimine) (PBPM) as a novel corrosion inhibitor was successfully synthesized and characterized in this work. The corrosion inhibition performance of PBPM for mild steel in 1.0 mol L-1 HCl medium was evaluated via weight loss measurements, electrochemical methods, scanning electron microscopy, contact angle measurements and quantum chemical calculations. The inhibition efficiency of PBPM is dependent on the concentration of PBPM and the test temperature. The highest inhibition efficiencies obtained by potentiodynamic and weight loss measurements in the presence of 800 mg L-1 PBPM at 30 degrees C were 93.93% and 94.04%, respectively. Potentiodynamic polarization tests showed that PBPM acts as an effective mixed-type corrosion inhibitor. The adsorption of PBPM on the surfaces of mild steel was found to obey Langmuir adsorption isotherm, with both physisorption and chemisorption. Scanning electron microscopy analyses affirmed the formation of a protective film on mild steel surfaces. Contact angle measurements revealed the hydrophobic nature of the surface modified by PBPM molecules applied in acidic corrosive solution. Furthermore, the influence of the molecular configuration of PBPM on the corrosion inhibition behaviour was investigated by DFT calculations and Fukui functions, and the protonated behaviour of PBPM in acidic system was also analysed. (C) 2021 Elsevier B.V. All rights reserved.
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