Revealing the relationships between alloy structure, composition and plastic deformation in a ternary alloy system by a combinatorial approach

A high-throughput approach based on magnetron co-sputtering of alloy libraries is employed to investigate mechanical properties of crystalline and amorphous alloys in a ternary palladium (Pd)-tungsten (W)-silicon (Si) system with the aim to reveal the difference in plastic deformation response and extract the relevant structure-property relationships of the alloys in the system. It was found that in contrast to crystalline alloys, the amorphous ones, i.e., metallic glasses, exhibited a much smaller fluctuation range in the plasticity parameters (E-r(2)/H and W-p/W-t), indicating a significant difference in the plastic deformation mechanism controlling the mechanical properties for the respective alloys. We propose that the inhomogeneous deformation of amorphous alloys localized in thin shear bands is responsible for the weaker compositional dependence of both plasticity parameters, while dislocation gliding in crystalline materials is significantly more dependent on the exact structure, thus resulting in a larger scattering range. Based on the representative efficient cluster packing model, a set of composition-dependent atomic structural models is proposed to figure out the structure-property relationships of amorphous alloys in Pd-W-Si alloy system. (C) 2021 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Automated summary

A high-throughput approach based on magnetron co-sputtering of alloy libraries is employed to investigate the mechanical properties of crystalline and amorphous alloys in a ternary palladium-tungsten-silicon system. The study reveals significant differences in plastic deformation mechanisms between amorphous and crystalline alloys, with amorphous alloys exhibiting a much smaller fluctuation range in plasticity parameters due to inhomogeneous deformation localized in thin shear bands. The proposed composition-dependent atomic structural models based on an efficient cluster packing model help to understand the structure-property relationships of amorphous alloys in the Pd-W-Si alloy system.